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KMID : 1024520180270070561
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Journal of the Environmental Sciences
2018 Volume.27 No. 7 p.561 ~ p.575
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Adsorption and Leaching Characteristics of Nonionic Pesticides in Soils of Jeju Island, Korea
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Jeon Si-Bum
Hyun Ik-Hyun
Lee Min-Gyu
Kam Sang-Kyu
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Abstract
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Agricultural soils around springwaters heavily affected by pesticide run-off and around wells considering the regional
characteristics were collected at 24 stations in Jeju Island, and the physicochemical properties and adsorption and leaching characteristics of four nonionic pesticides (diazinon, fenitrothion, alachlor, and metalaxyl) were investigated. The values of the major soil factors affecting the adsorption and leaching of pesticides, namely, soil pH(H2O), organic matter content, and cation exchange capacity (CEC), were in the range of 4.64 8.30, 0.9 13.1% and 12.7 31.7 meq/100 g, respectively. The Freundlich constant, KF value, which gives a measure of the adsorption capacity, decreased in the order of fenitrothion > diazinon > alachlor > metalaxyl, which was identical to their lower water solubility. Among the collected soils, the KF value was very highly correlated with organic matter content (r2 = 0.800 0.876) and CEC (r2 = 0.715 0.825) and showed a high correlation with clay content (r2 = 0.473 0.575) and soil pH(H2O) (r2 = 0.401 0.452). The leaching of pesticides in the soil column showed a reverse relationhip with their adsorption in soils, i.e., the pesticides leached more quickly for the soils with lower values of organic matter content and CEC among the soils and for the pesticides with higher water solubility.
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KEYWORD
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Adsorption, Leaching, Nonionic pesticides, Soils of Jeju Island, Physicochemical properties of soils, Freundlich constant (KF)
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